Issue 28, 2007
From the journal:

Chemical Communications

Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides†‡

Jean-Philippe Goddard,a   Catherine Gomez,a   Franck Brebion,a   Sophie Beauvière,a   Louis Fensterbank*a  and  Max Malacria*a  

* Corresponding authors

a Laboratoire de Chimie Organique (UMR CNRS 7611), Institut de chimie moléculaire FR 2769, Université Pierre et Marie Curie-Paris 6, case 229, 4 place Jussieu, 75252 Paris cedex 05, France
E-mail: louis.fensterbank@upmc.fr; max.malacria@upmc.fr
Web: http://www.umr7611.upmc.fr
Fax: (+) 33 1 44 27 73 60

Abstract

SET oxidation of bis-sulfinyl anions has enabled the uses of bis-sulfinyl radical as a synthetic equivalent of chiral acyl and methylene radicals involved in tandem reactions leading to the enantioselective construction of various carbo- and heterocyclic derivatives.

Graphical abstract: Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides

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Article information

DOI
https://doi.org/10.1039/B705284G
Article type
Communication
Submitted
10 Apr 2007
Accepted
21 May 2007
First published
21 Jun 2007

Chem. Commun., 2007, 2929-2931

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Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides

J. Goddard, C. Gomez, F. Brebion, S. Beauvière, L. Fensterbank and M. Malacria, Chem. Commun., 2007, 2929 DOI: 10.1039/B705284G

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