Issue 22, 2007
From the journal:

Chemical Communications

b-Bilene to a,c-biladiene transformation during syntheses of isoporphyrins and porphyrins†

Celinah Mwakwari,a   Frank R. Fronczeka  and  Kevin M. Smith*a  

* Corresponding authors

a Department of Chemistry, Louisiana State University, Baton Rouge, LA, USA
E-mail: kmsmith@lsu.edu
Fax: +1-225-578-3458
Tel: +1 225 578-7442

Abstract

Reaction of 1,19-di-unsubstituted b-bilene salts with α-ketoesters gives isoporphyrins, and eventually porphyrins, by way of an a,c-biladiene salt intermediate.

Graphical abstract: b-Bilene to a,c-biladiene transformation during syntheses of isoporphyrins and porphyrins

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Article information

DOI
https://doi.org/10.1039/B705182D
Article type
Communication
Submitted
05 Apr 2007
Accepted
30 Apr 2007
First published
10 May 2007

Chem. Commun., 2007, 2258-2260

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b-Bilene to a,c-biladiene transformation during syntheses of isoporphyrins and porphyrins

C. Mwakwari, F. R. Fronczek and K. M. Smith, Chem. Commun., 2007, 2258 DOI: 10.1039/B705182D

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