Issue 27, 2007
From the journal:

Chemical Communications

Bidentate N,O-prolinate ruthenium benzylidene catalyst highly active in RCM of disubstituted dienes†

Joseph S. M. Sameca  and  Robert H. Grubbs*a  

* Corresponding authors

a Division of Chemistry and Chemical Engineering, Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, USA
E-mail: rhg@caltech.edu
Fax: +1 (626) 564-9297
Tel: +1 (626) 395-6003

Abstract

The synthesis of a bidentate N,O-prolinate ruthenium benzylidene from commercially available starting materials and its activity in ring-closing metathesis of functionalized disubstituted dienes at 30 °C is disclosed.

Graphical abstract: Bidentate N,O-prolinate ruthenium benzylidene catalyst highly active in RCM of disubstituted dienes

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Article information

DOI
https://doi.org/10.1039/B704821A
Article type
Communication
Submitted
30 Mar 2007
Accepted
30 May 2007
First published
12 Jun 2007

Chem. Commun., 2007, 2826-2828

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Bidentate N,O-prolinate ruthenium benzylidene catalyst highly active in RCM of disubstituted dienes

J. S. M. Samec and R. H. Grubbs, Chem. Commun., 2007, 2826 DOI: 10.1039/B704821A

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