Issue 9, 2006
From the journal:

Chemical Communications

ACC-Oxidase like activity of a copper (ii)–ACC complex in the presence of hydrogen peroxide. Detection of a reaction intermediate at low temperature

Wadih Ghattas,a   Christian Gaudin,a   Michel Giorgi,a   Antal Rockenbauer,b   A. Jalila Simaan*a  and  Marius Régliera  

* Corresponding authors

a Laboratoire de Bioinorganique Structurale, UMR CNRS 6517, Université Paul Cézanne Aix-Marseille III, Service 432 Faculté des Sciences et Techniques, Av. Escadrille Normandie-Niemen, Marseille cedex 20, France
E-mail: jalila.simaan@univ.u-3mrs.fr
Fax: +33 4 91 92 32 08
Tel: +33 4 91 28 28 55

b Chemical Research Center, Hungarian Academy of Sciences H-1525 Budapest, PO Box 17, Hungary
Fax: +361 463-3819
Tel: +361 438-1131

Abstract

A Cu(II)–ACC complex [(Bpy)Cu(ACC)(H2O)]ClO4 (1) was prepared and its treatment with hydrogen peroxide gave rise to ethylene production in an ACC-Oxidase like activity. A brown species that could be a key intermediate in the reaction was detected at low temperature.

Graphical abstract: ACC-Oxidase like activity of a copper (ii)–ACC complex in the presence of hydrogen peroxide. Detection of a reaction intermediate at low temperature

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Article information

DOI
https://doi.org/10.1039/B515374C
Article type
Communication
Submitted
31 Oct 2005
Accepted
10 Jan 2006
First published
24 Jan 2006

Chem. Commun., 2006, 1027-1029

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ACC-Oxidase like activity of a copper (II)–ACC complex in the presence of hydrogen peroxide. Detection of a reaction intermediate at low temperature

W. Ghattas, C. Gaudin, M. Giorgi, A. Rockenbauer, A. J. Simaan and M. Réglier, Chem. Commun., 2006, 1027 DOI: 10.1039/B515374C

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