Issue 12, 2005

Steric engineering of C–F activation with lanthanoid formamidinates

Abstract

Reaction of lanthanum with Hg(C6F5)2 and bulky N,N′-bis(2,6-diisopropylphenyl)formamidine (HDippForm) in tetrahydrofuran gives [LaF{DippForm}2(THF)] with a rare terminal Ln–F bond, and a high yield of a novel functionalised formamidine, DippForm((CH2)4OC6F4H-o).

Graphical abstract: Steric engineering of C–F activation with lanthanoid formamidinates

Supplementary files

Article information

Article type
Communication
Submitted
21 Dec 2004
Accepted
31 Jan 2005
First published
15 Feb 2005

Chem. Commun., 2005, 1581-1583

Steric engineering of C–F activation with lanthanoid formamidinates

M. L. Cole, G. B. Deacon, P. C. Junk and K. Konstas, Chem. Commun., 2005, 1581 DOI: 10.1039/B419047E

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