Issue 17, 2004
From the journal:

Dalton Transactions

Diazenide and hydrazide(2−) derivatives of the [Re(CO)3]+ core

Roger Alberto,a   Andrew R. Cowley,b   Jonathan R. Dilworth,*c   Paul S. Donnellyc  and  Jennifer Prattc  

* Corresponding authors

a Institute of Inorganic Chemistry, University of Zürich, Winterhurerstrasse 190, Zürich, Switzerland

b Chemical Crystallography Laboratory, University of Oxford, 12 Mansfield Road, Oxford, UK

c Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, UK
E-mail: jon.dilworth@chem.ox.ac.uk
Fax: 01865-272690
Tel: 01865-285151

Abstract

Reaction of [ReBr3(CO)3]2− with aryldiazonium salts gives the Re(III) diazenide complexes [ReBr2(NNC6H4R-4)(CO)2]−. The attachment of a PhNHCS tethering group to pyridyl hydrazine generates a HYNIC related proligand which gives a stable chelated pyridyliumthiocarbazide(2−) derivative of the [Re(I)(CO)3]+ core.

Graphical abstract: Diazenide and hydrazide(2−) derivatives of the [Re(CO)3]+ core

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Article information

DOI
https://doi.org/10.1039/B407708C
Article type
Communication
Submitted
21 May 2004
Accepted
22 Jul 2004
First published
29 Jul 2004

Dalton Trans., 2004, 2610-2611

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Diazenide and hydrazide(2−) derivatives of the [Re(CO)3]+ core

R. Alberto, A. R. Cowley, J. R. Dilworth, P. S. Donnelly and J. Pratt, Dalton Trans., 2004, 2610 DOI: 10.1039/B407708C

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