Issue 17, 2004
From the journal:

Chemical Communications

α,β-Unsaturated imines from titanium hydroamination and functionalization by rhodium C–H activation†

Changsheng Cao,a   Yahong Li,a   Yanhui Shia  and  Aaron L. Odom*a  

* Corresponding authors

a Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA
E-mail: odom@cem.msu.edu

Abstract

Titanium pyrrolyl complexes are effective catalysts for the synthesis of α,β-unsaturated imines, which can be further functionalized using Rh-catalyzed alkene or alkyne insertion into the β-C–H bond.

Graphical abstract: α,β-Unsaturated imines from titanium hydroamination and functionalization by rhodium C–H activation

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Article information

DOI
https://doi.org/10.1039/B405620E
Article type
Communication
Submitted
19 Apr 2004
Accepted
04 Jun 2004
First published
07 Jul 2004

Chem. Commun., 2004, 2002-2003

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α,β-Unsaturated imines from titanium hydroamination and functionalization by rhodium C–H activation

C. Cao, Y. Li, Y. Shi and A. L. Odom, Chem. Commun., 2004, 2002 DOI: 10.1039/B405620E

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