The H and D atom elimination mechanisms in the photodissociation of jet cooled pyrrole and pyrrole-d₁ have been studied by photofragment velocity map imaging. The molecules were excited to the 1 ¹A₂ (πσ*) state at λ = 243 nm and to the 1 ¹B₂ (ππ*) state at λ = 217 nm. H/D atoms were detected by (2 + 1) resonance enhanced multiphoton ionization (REMPI) at λ = 243 nm. The analysis of the images and the resulting translational energy distributions from the 1 ¹A₂ state demonstrates the existence of two decay pathways, fast mode-specific cleavage of the NH bond in the excited state (channel A) and internal conversion (IC) to the electronic ground state (S₀) followed by unimolecular decomposition of the vibrationally hot S₀ molecules (channel B). The angular distributions of the H/D atoms from the direct dissociation in the excited state are strongly anisotropic, whereas the decay of the S₀ molecules leads to spatially isotropic distributions. The results at λ = 217 nm indicate that the 1 ¹B₂ state undergoes an ultrafast radiationless transition to 1 ¹A₂ followed by the abovementioned direct mode-specific NH bond fission on the 1 ¹A₂ potential energy surface (channel A′) or conversion to S₀ and subsequent unimolecular decomposition (channel B′). The latter pathway may also be initiated by a direct relaxation from 1 ¹B₂ to S₀. The anisotropy parameter of β ≈ −1 for the direct NH bond fission at λ = 217 nm is in accordance with the expectations for a perpendicular electronic excitation and a dissociation lifetime that is short compared to the rotational period of the molecules. The fast decay dynamics of both excited electronic states can be rationalized with reference to the theoretically predicted conical intersections between the ππ*, πσ*, and S₀ potential energy surfaces and the antibonding nature of the πσ* potential energy surface with respect to the NH bond [A. L. Sobolewski, W. Domcke, C. Dedonder-Lardeux and C. Jouvet, Phys. Chem. Chem. Phys. 2002, 4, 1093].