Issue 10, 2004

An achiral, anticlinic-promoting, smectic liquid crystal architecture

Abstract

We describe a simple, achiral, terminal chain that appears to readily convert the synclinic SmC phase to the anticlinic SmCA phase. If the α-carbon of a terminal chain is di-substituted, i.e., if either 1,1-dimethylpentyloxycarbonyl or 1,1-dimethylhexyloxycarbonyl is used instead of the usual chiral chain, 1-methylheptyloxycarbonyl, the terminal chain in the well known, antiferroelectric mesogen MHPOBC, an anticlinic SmCA phase is observed exclusively below the SmA phase. Moreover, the dimethyl-substituted terminal chain can induce the SmCA phase in very ordinary mesogens: n-hexyl decyloxybiphenyl carboxylate (HDBC) changes its conventional synclinic SmC phase into the anticlinic SmCA phase when mixed with a molecule having the same HDBC core but containing the dimethyl-substituted terminal chain. The simple structure of this achiral terminal chain suggests that a generic mechanism is responsible for tilt sense propagation in smectics: we posit that subtle intra-layer packing arrangements within the aliphatic stratum give rise to a topographic pattern on the layer interface, and that this pattern communicates tilt sense preferences, anticlinic or synclinic, from layer to layer.

Graphical abstract: An achiral, anticlinic-promoting, smectic liquid crystal architecture

Article information

Article type
Paper
Submitted
20 Jan 2004
Accepted
18 Mar 2004
First published
26 Apr 2004

J. Mater. Chem., 2004,14, 1554-1559

An achiral, anticlinic-promoting, smectic liquid crystal architecture

J. Thisayukta and E. T. Samulski, J. Mater. Chem., 2004, 14, 1554 DOI: 10.1039/B400937A

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