Issue 13, 2004
From the journal:

Chemical Communications

A facile reaction of imines with telluronium allylide. Highly stereoselective synthesis of vinylaziridines†

Wei-Wei Liao,a   Xian-Ming Denga  and  Yong Tang*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, P. R. China
E-mail: tangy@mail.sioc.ac.cn
Fax: (+86) 21-64166128

Abstract

The reaction of telluronium allylides with alkylimines, generated in situ from α-amidoalkyl sulfones, affords cis-alkylvinylarizidines with good stereoselectivity in good yields. However, the same ylides react with N-aryl imines to provide trans-vinylaziridines.

Graphical abstract: A facile reaction of imines with telluronium allylide. Highly stereoselective synthesis of vinylaziridines

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B400464G
Article type
Communication
Submitted
12 Jan 2004
Accepted
26 Apr 2004
First published
01 Jun 2004

Chem. Commun., 2004, 1516-1517

Permissions

Request permissions

A facile reaction of imines with telluronium allylide. Highly stereoselective synthesis of vinylaziridines

W. Liao, X. Deng and Y. Tang, Chem. Commun., 2004, 1516 DOI: 10.1039/B400464G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements