Issue 1, 2004
From the journal:

Chemical Communications

3,6-Dioxypyridazine bridged tungsten–tungsten quadruple bonds. Comparisons of electron delocalisation with oxalate bridged compounds†‡

Malcolm H. Chisholm,*a   Robin J. H. Clark,*b   Christopher M. Hadad*a  and  Nathan J. Patmorea  

* Corresponding authors

a Department of Chemistry, The Ohio State University, 100 W. 18th Avenue, Columbus, OH 43210-1173, USA
E-mail: chisholm@chemistry.ohio-state.edu.

b Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, UK
E-mail: r.j.h.clark@ucl.ac.uk

Abstract

The preparation and characterisation of the tungsten–tungsten quadruply bonded, 3,6-dioxypyridazine bridged complex [(tBuCO2)3W2]2(μ-H2C4N2O2) and its single electron oxidised radical cation are reported and, when compared with related bridged dimolybdenum complexes, reveal a different mechanism of electronic coupling from that seen in related oxalate bridged systems.

Graphical abstract: 3,6-Dioxypyridazine bridged tungsten–tungsten quadruple bonds. Comparisons of electron delocalisation with oxalate bridged compounds

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B310982H
Article type
Communication
Submitted
10 Sep 2003
Accepted
28 Oct 2003
First published
20 Nov 2003

Chem. Commun., 2004, 80-82

Permissions

Request permissions

3,6-Dioxypyridazine bridged tungsten–tungsten quadruple bonds. Comparisons of electron delocalisation with oxalate bridged compounds

M. H. Chisholm, R. J. H. Clark, C. M. Hadad and N. J. Patmore, Chem. Commun., 2004, 80 DOI: 10.1039/B310982H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements