Issue 2, 2004

Unprecedented tubular channels assemblies afforded by alkyl-substituted oxamide oxime metal complexes

Abstract

The synthesis of an oxamide oxime substituted with hexyl chains, together with its nickel(II) (1) and palladium(II) (2) complexes, is described. Both complexes crystallize in the hexagonal space group R[3 with combining macron] (No 148). In the crystal the complex molecules are linked by hydrogen bonds involving the oximic oxygen atoms and the amino nitrogen atoms to build infinite tubular channels partly filled by the hexyl chains and self-organized in two-dimensional hexagonal arrays.

Graphical abstract: Unprecedented tubular channels assemblies afforded by alkyl-substituted oxamide oxime metal complexes

Supplementary files

Article information

Article type
Letter
Submitted
04 Jul 2003
Accepted
30 Oct 2003
First published
19 Dec 2003

New J. Chem., 2004,28, 177-179

Unprecedented tubular channels assemblies afforded by alkyl-substituted oxamide oxime metal complexes

G. Gümüş, V. Ahsen, C. Lebrun, D. Luneau and J. Pécaut, New J. Chem., 2004, 28, 177 DOI: 10.1039/B307783G

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