Issue 18, 2003

Amination and [2,3]-sigmatropic rearrangement of propargylic sulfides using a ketomalonate-derived oxaziridine: synthesis of N-allenylsulfenimides

Abstract

Amination of propargylic sulfides with a ketomalonate-derived oxaziridine under metal free conditions gives N-Boc-N-allenylsulfenimides via [2,3]-sigmatropic rearrangement.

Graphical abstract: Amination and [2,3]-sigmatropic rearrangement of propargylic sulfides using a ketomalonate-derived oxaziridine: synthesis of N-allenylsulfenimides

Article information

Article type
Communication
Submitted
09 Jul 2003
Accepted
08 Aug 2003
First published
14 Aug 2003

Org. Biomol. Chem., 2003,1, 3142-3143

Amination and [2,3]-sigmatropic rearrangement of propargylic sulfides using a ketomalonate-derived oxaziridine: synthesis of N-allenylsulfenimides

A. Armstrong, R. S. Cooke and S. E. Shanahan, Org. Biomol. Chem., 2003, 1, 3142 DOI: 10.1039/B307722E

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