The first PdII complex of a non-heteroatom stabilised carbene ligand

Martin Bröring; Carsten D. Brandt; Sascha Stellwag

doi:10.1039/B307160J

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The first Pd^II complex of a non-heteroatom stabilised carbeneligand

Martin Bröring,*^a Carsten D. Brandt^a and Sascha Stellwag^a

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* Corresponding authors

^a Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, D-35043 Marburg, Germany
E-mail: Martin.Broering@chemie.uni-marburg.de

Abstract

Di(p-tolyl)diazomethane reacts with the tripyrrinate TrpyPdOAc^F1 after activation with NaBAr^F to yield the first stable Pd^II complex 2 of a non-Arduengo type carbene ligand, which could be characterised by X-ray crystallography.

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Supplementary files

Crystal structure data TXT (45K)

Article information

DOI: https://doi.org/10.1039/B307160J
Article type: Communication
Submitted: 23 Jun 2003
Accepted: 01 Aug 2003
First published: 11 Aug 2003

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Chem. Commun., 2003, 2344-2345

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The first Pd^II complex of a non-heteroatom stabilised carbene ligand

M. Bröring, C. D. Brandt and S. Stellwag, Chem. Commun., 2003, 2344 DOI: 10.1039/B307160J

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