Issue 17, 2003
From the journal:

Chemical Communications

First example of an infinite polybromide 2D-network†

M. Carla Aragoni,a   Massimiliano Arca,*a   Francesco A. Devillanova,*a   Francesco Isaia,a   Vito Lippolis,a   Annalisa Mancini,a   Luca Pala,a   Alexandra M. Z. Slawinb  and  J. Derek Woollinsb  

* Corresponding authors

a Dipartimento di Chimica Inorganica ed Analitica, S.S. 554 bivio per Sestu, Cagliari, 09042 Monserrato, Italy
E-mail: marca@unica.it
Fax: +39 070 675 4456
Tel: +39 070 675 4483

b School of Chemistry, University of St. Andrews, St. Andrews, Fife, UK

Abstract

The reaction of the neutral dithiolene [Pd(Et2timdt)2] (Et2timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with an excess of Br2 yielded few crystals of [1Et·2Br]2+(Br−)2(Br2)3 as a by-product (1Et = 4,5,9,10-tetrathiocino-[1,2-b:5,6-b′]-1,3,6,8-tetraethyl-diimidazolyl-2,7-dithione); X-ray diffraction analysis showed that this compound represents the first example of a polybromide 2D-network templated by [1Et·2Br]+2 dications, and featuring all the Br–Br distances shorter than those found in solid state bromine.

Graphical abstract: First example of an infinite polybromide 2D-network

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Article information

DOI
https://doi.org/10.1039/B306841B
Article type
Communication
Submitted
17 Jun 2003
Accepted
08 Jul 2003
First published
28 Jul 2003

Chem. Commun., 2003, 2226-2227

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First example of an infinite polybromide 2D-network

M. C. Aragoni, M. Arca, F. A. Devillanova, F. Isaia, V. Lippolis, A. Mancini, L. Pala, A. M. Z. Slawin and J. D. Woollins, Chem. Commun., 2003, 2226 DOI: 10.1039/B306841B

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