Issue 20, 2002
From the journal:

Chemical Communications

Small reorganisation energy and unique stabilisation of zwitterionic C60–acceptor moieties†

Dirk M. Guldi,*a   Chuping Luo,a   Tatiana Da Ros,b   Susanna Bosib  and  Maurizio Prato*b  

* Corresponding authors

a Radiation Laboratory, University of Notre Dame, Notre Dame, IN, USA
E-mail: guldi.1@nd.edu
Fax: 1 574 631 8068
Tel: 1 574 631 7441

b Dipartimento di Scienze Farmaceutiche, Università di Trieste, Piazzale Europa, 1, Trieste, Italy
E-mail: prato@univ.trieste.it
Fax: 39 040 52572
Tel: 39 040 558 7883

Abstract

Fulleropyrrolidine- and fulleropyrrolidinium-based donor–acceptor ensembles, C60–Fc, were tested in view of intrinsic reorganisation energies for light-induced electron transfer events; overall, the zwitterionic character of the reduced fulleropyrrolidinium acceptor plays a central role in accelerating charge separation and decelerating charge recombination.

Graphical abstract: Small reorganisation energy and unique stabilisation of zwitterionic C60–acceptor moieties

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Article information

DOI
https://doi.org/10.1039/B206930J
Article type
Communication
Submitted
17 Jul 2002
Accepted
10 Sep 2002
First published
24 Sep 2002

Chem. Commun., 2002, 2320-2321

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Small reorganisation energy and unique stabilisation of zwitterionic C60–acceptor moieties

D. M. Guldi, C. Luo, T. Da Ros, S. Bosi and M. Prato, Chem. Commun., 2002, 2320 DOI: 10.1039/B206930J

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