Issue 5, 2002
From the journal:

Chemical Communications

Reactive species formed from N-benzyloxycarbonyl α-aminophosphonochloridates and triethylamine: probable identity and implications for synthesis†

Paul M. Cullisa  and  Martin J. P. Hargera  

a Department of Chemistry, University of Leicester, Leicester, UK

Abstract

The sterically congested phosphonochloridate BnOCONHCMe2P(O)(OMe)Cl reacts rapidly with Et3N to give what is thought to be an oxazaphospholine oxide 7 (and Et3NHCl); unhindered BnOCONHCH2P(O)(OMe)Cl seems to react in the same way, in which case the product is not a phosphonylammonium salt as has been suggested.

Graphical abstract: Reactive species formed from N-benzyloxycarbonyl α-aminophosphonochloridates and triethylamine: probable identity and implications for synthesis

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Article information

DOI
https://doi.org/10.1039/B109231F
Article type
Communication
Submitted
10 Oct 2001
Accepted
18 Dec 2001
First published
13 Feb 2002

Chem. Commun., 2002, 458-459

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Reactive species formed from N-benzyloxycarbonyl α-aminophosphonochloridates and triethylamine: probable identity and implications for synthesis

P. M. Cullis and M. J. P. Harger, Chem. Commun., 2002, 458 DOI: 10.1039/B109231F

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