Issue 24, 2001
From the journal:

Chemical Communications

Highly enantioselective synthesis via dynamic kinetic resolution under transfer hydrogenation using Ru(η6-arene)-N-perfluorosulfonyl-1,2-diamine catalysts: a first insight into the relationship of the ligand’s pKa and the catalyst activity

Barbara Mohar,a   Alain Valleix,b   Jean-Roger Desmurs,c   Marc Felemez,d   Alain Wagner*d  and  Charles Mioskowski*bd  

* Corresponding authors

a National Institute of Chemistry, Hajdrihova 19, Ljubljana, Slovenia

b CEA-Service des Molécules Marquées, Gif sur Yvette, France

c Rhodia Chimie, 85 Avenue Freres Perret, Saint Fons, France

d UMR 7514 du CNRS, Faculté de Pharmacie, 74 Route du Rhin, Strasbourg, France
E-mail: alwag@aspirine.u-strasbg.fr; mioskowski@bioorga.u-strasbg.fr
Fax: +33 3 90 24 43 06
Tel: +33 3 90 24 42 95

Abstract

β-(3,4-Dimethoxyphenyl)serine methyl ester was obtained in high diastereomeric and enantiomeric excesses under transfer hydrogenation using chiral Ru(η6-arene)-N-perfluorosulfonyl-1,2-diamine catalysts.

Graphical abstract: Highly enantioselective synthesis via dynamic kinetic resolution under transfer hydrogenation using Ru(η6-arene)-N-perfluorosulfonyl-1,2-diamine catalysts: a first insight into the relationship of the ligand’s pKa and the catalyst activity

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Article information

DOI
https://doi.org/10.1039/B107822B
Article type
Communication
Submitted
30 Aug 2001
Accepted
22 Oct 2001
First published
13 Nov 2001

Chem. Commun., 2001, 2572-2573

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Highly enantioselective synthesis via dynamic kinetic resolution under transfer hydrogenation using Ru(η6-arene)-N-perfluorosulfonyl-1,2-diamine catalysts: a first insight into the relationship of the ligand’s pKa and the catalyst activity

B. Mohar, A. Valleix, J. Desmurs, M. Felemez, A. Wagner and C. Mioskowski, Chem. Commun., 2001, 2572 DOI: 10.1039/B107822B

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