Issue 3, 2002

Synthesis and near-infrared luminescence of 3d-4f bi-metallic Schiff base complexes

Abstract

The reaction of the zinc(II) Schiff base complex ZnL [H2L = N,N′-bis(3-methoxysalicylidene)ethylene-1,2-diamine] with one equivalent of Ln(NO3)3·xH2O (Ln = Nd, Ho, Er or Yb) gives the neutral 3d-4f bi-metallic Schiff base complexes [Zn(NO3)(μ-L)Ln(NO3)2(H2O)], which in solution exhibit emission corresponding to the Ln(III) ions (Ln = Nd, Er and Yb) in the near-infrared region.

Supplementary files

Article information

Article type
Letter
Submitted
11 May 2001
Accepted
20 Dec 2001
First published
14 Feb 2002

New J. Chem., 2002,26, 275-278

Synthesis and near-infrared luminescence of 3d-4f bi-metallic Schiff base complexes

W. Wong, H. Liang, W. Wong, Z. Cai, K. Li and K. Cheah, New J. Chem., 2002, 26, 275 DOI: 10.1039/B104175B

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