Issue 6, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates: [Zn(2,2′-bipyridine)(VO2)(PO4)], [Zn(2,2′:6′,2″-terpyridine)(VO2)(PO4)], and [Zn(1,10-phenanthroline)(ZnVO)(PO4)2]

Robert C. Finna  and  Jon Zubieta*a  

* Corresponding authors

a Department of Chemistry, Syracuse University, Syracuse, NY 13244, USA

Abstract

The hydrothermal reactions of zinc oxide, phosphoric acid, sodium orthovanadate, and the appropriate polyimine ligand at 200 °C for 95, 68, and 42.5 h, respectively, have yielded three novel compounds, [Zn(bpy)(VO2)(PO4)] (1), [Zn(terpy)(VO2)(PO4)] (2), and [Zn(o-phen)(ZnVO)(PO4)2] (3). Compounds 1 and 2 are both one-dimensional chains with discreet {V2P2O4} rings linked through zinc organoimine components. Compound 3 exhibits unusual {V2P4O18} subunits which are bound through fully bridging zinc tetrahedra to form a two-dimensional sheet. The sheet is further surface decorated by {Zn(o-phen)}2+ moieties.

Graphical abstract: Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates: [Zn(2,2′-bipyridine)(VO2)(PO4)], [Zn(2,2′:6′,2″-terpyridine)(VO2)(PO4)], and [Zn(1,10-phenanthroline)(ZnVO)(PO4)2]

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Article information

DOI
https://doi.org/10.1039/B103994F
Article type
Paper
Submitted
20 Apr 2001
Accepted
07 Dec 2001
First published
08 Feb 2002

J. Chem. Soc., Dalton Trans., 2002, 856-861

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Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates: [Zn(2,2′-bipyridine)(VO2)(PO4)], [Zn(2,2′:6′,2″-terpyridine)(VO2)(PO4)], and [Zn(1,10-phenanthroline)(ZnVO)(PO4)2]

R. C. Finn and J. Zubieta, J. Chem. Soc., Dalton Trans., 2002, 856 DOI: 10.1039/B103994F

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