Issue 12, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands

Vivian Wing-Wah Yam,*a   Ben Wai-Kin Chu,a   Chi-Chiu Koa  and  Kung-Kai Cheunga  

* Corresponding authors

a Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong SAR, People’s Republic of China
E-mail: wwyam@hku.hk
Fax: (852)2857-1586

Abstract

A series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [[upper bond 1 start]Ru(phen)2{[double bond, length as m-dash]C(CH2Ph)NHC[upper bond 1 end]6H4}]CF3SO3, [[upper bond 1 start]Ru(bpy)2{[double bond, length as m-dash]C(CH2Ph)NMeC[upper bond 1 end]6H4}]PF6 and [[upper bond 1 start]Ru(bpy)2{[double bond, length as m-dash]C(CH2C4H3S)NHC[upper bond 1 end]6H4}]CF3SO3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies.

Graphical abstract: Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B100696G
Article type
Paper
Submitted
18 Jan 2001
Accepted
12 Apr 2001
First published
23 May 2001

J. Chem. Soc., Dalton Trans., 2001, 1911-1919

Permissions

Request permissions

Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands

V. Wing-Wah Yam, B. Wai-Kin Chu, C. Ko and K. Cheung, J. Chem. Soc., Dalton Trans., 2001, 1911 DOI: 10.1039/B100696G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements