Issue 21, 2000
From the journal:

Chemical Communications

A novel route to advanced model systems for silica-immobilized olefin polymerization catalysts

Frank T. Edelmann,*a   Stephan Gießmanna  and  Axel Fischera  

* Corresponding authors

a Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, D-39106, Magdeburg, Germany.
E-mail: Frank.Edelmann@vst.uni-magdeburg.de

Abstract

Constituting a novel synthetic route to model compounds for titanium catalysts immobilized on silica, the disilylated silsesquioxane derivative Cy7Si7O9(OH)(OSiMe3)2 2a, has been reacted with the ‘tucked-in’ fulvene complex Cp*Ti- (C5Me4CH2) to give the titanium(III) silsesquioxane Cp*2Ti[Cy7Si7O10(OSiMe3 )2] 3, while treatment of Cp*Ti- (C5Me4CH2) with Cy7Si7O9(OH)2(OSiMe3 ) 2b affords the mono(pentamethylcyclopentadienyl) complex Cp*Ti[Cy7- Si7O11(OSiMe3)][Cy7Si7 O10(OH)(OSiMe3)] 4 which is an advanced model compound for a catalytically active titanium center on a silica surface.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B007854I
Article type
Communication
Submitted
26 Apr 2000
Accepted
28 Sep 2000
First published
19 Oct 2000

Chem. Commun., 2000, 2153-2154

Permissions

Request permissions

A novel route to advanced model systems for silica-immobilized olefin polymerization catalysts

F. T. Edelmann, S. Gießmann and A. Fischer, Chem. Commun., 2000, 2153 DOI: 10.1039/B007854I

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements