The dilithio boraamidinate complexes {Li2[RB(NBut)2]}x (R = Bun, x = 2 and R = Me, x = 3), prepared unexpectedly by treating B[N(H)But]3 with 3 equiv. LiR, represent the first structurally characterized s-block metal derivatives of the boraamidinate ion.
A new route to dilithio boraamidinates: formation and X-ray structures of the dimeric and trimeric clusters {Li2[RB(NBut)2]}x (R = Bun, x = 2 and R = Me, x = 3)
J. K. Brask, T. Chivers and G. Schatte, Chem. Commun., 2000, 1805 DOI: 10.1039/B005852L
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