Issue 5, 2000
From the journal:

Journal of Materials Chemistry

S. Neeraja  and  Srinivasan Natarajan*a  

* Corresponding authors

a Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore, India
E-mail: raj@jncasr.as.in
Fax: ; Fax: +(080)-846-2766

Abstract

A zinc chlorophosphate, of the composition [C6NH14][ZnCl(HPO4)], with a layered architecture has been synthesized, for the first time, in the presence of cyclohexylamine as the structure-directing agent. The structure comprises a network of ZnO3Cl and PO4 tetrahedra forming macroanionic layers with four- and eight-membered apertures. Charge compensation is achieved by the protonated amine occupying inter-lamellar space and interacts with the framework via hydrogen bonding. The crystal structure of the new compound was determined.

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Article information

DOI
https://doi.org/10.1039/A910288O
Article type
Paper
Submitted
23 Dec 1999
Accepted
24 Feb 2000
First published
13 Apr 2000

J. Mater. Chem., 2000,10, 1171-1175

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Synthesis and structure of an open-framework chlorophosphate, [C6NH14][ZnCl(HPO4)]

S. Neeraj and S. Natarajan, J. Mater. Chem., 2000, 10, 1171 DOI: 10.1039/A910288O

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