Issue 14, 2000
From the journal:

Chemical Communications

Solid state coordination chemistry of oxovanadium phosphates: hydrothermal syntheses and structures of the network and chain phosphate phases [{Cu(bpy)}2(VO)3(PO4)2 (HPO4)2]·2H2O and [{Cu(terpy)}2(VO2)3(PO4 )(HPO4)2]

Robert Finna  and  Jon Zubieta*a  

* Corresponding authors

a Department of Chemistry, Syracuse University, Syracuse, NY, USA.
E-mail: jazubiet@mailbox.syr.edu

Abstract

The hydrothermal reactions of Cu2O, the appropriate polypyridine ligand, Na3VO4, H3PO4 and H2O at 200 °C yield the two-dimensional material [{Cu(bpy)}2(VO)3- (PO4)2(HPO4)2]·2H2 O and the one-dimensional phosphate [{Cu(terpy)}2(VO2)3(PO4 )(HPO4)2], examples of the structure-directing role of secondary metal–ligand subunits on the architectures of vanadium phosphates.

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Article information

DOI
https://doi.org/10.1039/A909743K
Article type
Communication
Submitted
08 Dec 1999
Accepted
16 May 2000
First published
23 Jun 2000

Chem. Commun., 2000, 1321-1322

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Solid state coordination chemistry of oxovanadium phosphates: hydrothermal syntheses and structures of the network and chain phosphate phases [{Cu(bpy)}2(VO)3(PO4)2 (HPO4)2]·2H2O and [{Cu(terpy)}2(VO2)3(PO4 )(HPO4)2]

R. Finn and J. Zubieta, Chem. Commun., 2000, 1321 DOI: 10.1039/A909743K

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