Issue 12, 1999
From the journal:

New Journal of Chemistry

Simple, low-cost synthetic route to potentially polymerizable silatranes

Hengqin Cheng  and  Richard M. Laine  

Abstract

Silatrane glycol, 2, can be synthesized in kilogram quantities in one step from silica. Compound 2 is unusual for a silicon alkoxy compound as it is water soluble and water stable. Silatrane glycol 2 can be reacted with acetic anhydride to produce 1-acetoxysilatrane, 4. Compound 4 undergoes facile ligand exchange allowing the synthesis of a number of reactive compounds including: 1-methacryloxysilatrane 5, 1-allyloxysilatrane 6 and 2-[(propen-2-yloxy)ethanoxy]silatrane 7 all of which are potentially useful for producing silatrane-containing polymers.

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Article information

DOI
https://doi.org/10.1039/A908291C
Article type
Paper

New J. Chem., 1999,23, 1181-1186

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Simple, low-cost synthetic route to potentially polymerizable silatranes

H. Cheng and R. M. Laine, New J. Chem., 1999, 23, 1181 DOI: 10.1039/A908291C

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