Issue 16, 1999
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Intramolecular N–H insertion of α-diazocarbonyls catalyzed by Cu(acac)2: An efficient route to derivatives of 3-oxoazetidines, 3-oxopyrrolidines and 3-oxopiperidines

Jianbo Wang,   Yihua Hou  and  Peng Wu  

Abstract

Cu(acac)2 was found to be an efficient catalyst for the intramolecular N–H insertion by carbenoids. The competitive intramolecular C–H insertion by carbenoids is not a problem in the diazo decomposition reaction with Cu(acac)2 as catalyst. The reaction provided derivatives of 3-oxoazetidine, 3-oxopyrrolidine and 3-oxopiperidine in moderate to good yields.

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Article information

DOI
https://doi.org/10.1039/A903722E
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 2277-2280

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Intramolecular N–H insertion of α-diazocarbonyls catalyzed by Cu(acac)2: An efficient route to derivatives of 3-oxoazetidines, 3-oxopyrrolidines and 3-oxopiperidines

J. Wang, Y. Hou and P. Wu, J. Chem. Soc., Perkin Trans. 1, 1999, 2277 DOI: 10.1039/A903722E

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