Issue 18, 1999
From the journal:

Chemical Communications

Reactions of water soluble iron(II) and cobalt(II) porphyrins with nitric oxide. Implications for the reactivity of NO and biologically relevant metal centers

Leroy E. Laverman  and  Peter C. Ford  

Abstract

The entropies and volumes of activation (ΔS‡on and ΔV‡on) for the fast reactions (kon > 109 dm3 mol–1 s–1) reaction of NO with the water soluble iron(II) porphyrin complexes FeII(TPPS) [TPPS = tetrakis(4-sulfonatophenyl)porphinato] and FeII(TMPS) [TMPS = tetrakis(sulfonatomesityl)porphinato] are small and positive indicating that these reactions are dominated by the diffusion processes as is the analogous formation of the cobalt(II) complex CoII(TPPS)(NO).

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Article information

DOI
https://doi.org/10.1039/A902725D
Article type
Paper

Chem. Commun., 1999, 1843-1844

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Reactions of water soluble iron(II) and cobalt(II) porphyrins with nitric oxide. Implications for the reactivity of NO and biologically relevant metal centers

L. E. Laverman and P. C. Ford, Chem. Commun., 1999, 1843 DOI: 10.1039/A902725D

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