Issue 11, 1999

Synthesis and luminescence behaviour of mixed-metal rhenium(I)–copper(I) and –silver(I) alkynyl complexes. X-Ray crystal structures of [{η2-Re(CO)3(bpy)(C[triple bond, length half m-dash]CPh)}2Cu]PF6 and [{η2-Re(CO)3(bpy)(C[triple bond, length half m-dash]CPh)}2Ag]PF6

Abstract

Two mixed-metal rhenium(I)–copper(I) and –silver(I) alkynyl complexes, [{η2-Re(CO)3(bpy)(C[triple bond, length half m-dash]CPh)}2Cu]PF6 1 and [{η2-Re(CO)3(bpy)(C[triple bond, length half m-dash]CPh)}2Ag]PF6 2, have been synthesized and shown to exhibit rich luminescence behaviour; the X-ray crystal structures of both complexes have also been determined.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 1013-1014

Synthesis and luminescence behaviour of mixed-metal rhenium(I)–copper(I) and –silver(I) alkynyl complexes. X-Ray crystal structures of [{η2-Re(CO)3(bpy)(C[triple bond, length half m-dash]CPh)}2Cu]PF6 and [{η2-Re(CO)3(bpy)(C[triple bond, length half m-dash]CPh)}2Ag]PF6

V. Wing-Wah Yam, S. Hung-Fai Chong, K. Man-Chung Wong and K. Cheung, Chem. Commun., 1999, 1013 DOI: 10.1039/A902273B

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