Issue 17, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

A new route to tris(pyrazolyl)borate ligands and new structural variations in TlTp complexes †

Christoph Janiak,   Lothar Braun  and  Frank Girgsdies  

Abstract

Tris(pyrazolyl)borate ligands were synthesized by a new route from MeBBr2 and pyrazole derivatives under very mild conditions at room temperature to give TlL complexes. For L = [MeB(3,5-Me2pz)3]– a bridging co-ordination of the ligand is found, interpreted as sterically enforced upon comparison with the structures for L = [MeB(3-Mepz)3]– and [HB(3,5-Me2pz)3]–.

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Article information

DOI
https://doi.org/10.1039/A902264C
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 3133-3136

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A new route to tris(pyrazolyl)borate ligands and new structural variations in TlTp complexes †

C. Janiak, L. Braun and F. Girgsdies, J. Chem. Soc., Dalton Trans., 1999, 3133 DOI: 10.1039/A902264C

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