Issue 22, 1998

Cyclopentadienyl titanium chlorides containing ortho-(1-naphthyl)phenoxide ligation

Abstract

A series of mono-cyclopentadiene derivatives of titanium containing ortho-(1-naphthyl)phenoxide ligands have been studied; the Ti–Ti distance in the d1–d1 species [Cp(ArO)Ti(µ-Cl)2Ti(OAr)Cp] is exactly intermediate between that found in paramagnetic [Cp2Ti(µ-Cl)2TiCp2] and diamagnetic [(ArO)2Ti(µ-Cl)2Ti(OAr)2].

Article information

Article type
Paper

Chem. Commun., 1998, 2425-2426

Cyclopentadienyl titanium chlorides containing ortho-(1-naphthyl)phenoxide ligation

J. S. Vilardo, M. G. Thorn, P. E. Fanwick and I. P. Rothwell, Chem. Commun., 1998, 2425 DOI: 10.1039/A805034A

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