Issue 10, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and characterisation of the first E-unidentate [Ph2P(O)NP(E)Ph2]– metal complexes [Au{Ph2P(O)NP(E)Ph2-E }{Ph2P(O)NHPPh2}] and [Pd{Ph2P(O)NP(E)Ph2-E }2(H2NCH2CH2NH2)] (E = S or Se)

Alexandra M. Z. Slawin,   Martin B. Smith  and  J. Derek Woollins  

Abstract

Chloride metathesis of [AuCl(HL)] [HL = Ph2P(O)NHPPh2] or [PdCl2(en)] (en = ethane-1,2-diamine) in CH3OH with either 1 (or 2) equivalents of [Ph2P(O)NP(E)Ph2]– (E = S or Se) gave the neutral compounds [Au{Ph2P(O)NP(E)Ph2-E }(HL)] or [Pd{Ph2P(O)NP(E)Ph2-E }2(en)] respectively; the anionic ligands in these complexes adopt a new bonding mode and furthermore are involved in intramolecular N–H · · · OP hydrogen bonding with HL or en.

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Article information

DOI
https://doi.org/10.1039/A801856A
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 1537-1540

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Synthesis and characterisation of the first E-unidentate [Ph2P(O)NP(E)Ph2]– metal complexes [Au{Ph2P(O)NP(E)Ph2-E }{Ph2P(O)NHPPh2}] and [Pd{Ph2P(O)NP(E)Ph2-E }2(H2NCH2CH2NH2)] (E = S or Se)

A. M. Z. Slawin, M. B. Smith and J. Derek Woollins, J. Chem. Soc., Dalton Trans., 1998, 1537 DOI: 10.1039/A801856A

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