Issue 11, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, emission and molecular orbital studies of luminescent zirconium thiolate complexes. Crystal structure of [Zr(η5-C5Me5)2(SBun)2]

Vivian Wing-Wah Yam,   Gui-Zhong Qi  and  Kung-Kai Cheung  

Abstract

A series of luminescent zirconium thiolate complexes [Zr(η5-C5Me5)2(ER)2] (E = S, R = Bun, C6H4But-p, C6H4Cl-p or Ph; E = Se, R = Ph) have been synthesized by the reaction of [Zr(η5-C5Me5)2Cl2] with NaER, and shown to exhibit rich luminescence behavior. The crystal structure of [Zr(η5-C5Me5)2(SBun)2] has been determined. Fenske–Hall molecular orbital calculations on the zirconium thiolate complexes revealed a thiolate-based HOMO and a LUMO that is mainly composed of zirconium d character.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/A800122G
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 1819-1824

Permissions

Request permissions

Synthesis, emission and molecular orbital studies of luminescent zirconium thiolate complexes. Crystal structure of [Zr(η5-C5Me5)2(SBun)2]

V. Wing-Wah Yam, G. Qi and K. Cheung, J. Chem. Soc., Dalton Trans., 1998, 1819 DOI: 10.1039/A800122G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements