Issue 3, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and crystal structure of the tris(amide) cations [M{N(SiMe3)2}3]+ (M = Zr or Hf ): evidence for M–Si–C interactions

Jane R. Galsworthy,   Malcolm L. H. Green,   Neil Maxted  and  Matthias Müller  

Abstract

Reaction of the strong Lewis acid B(C6F5)3 with [M{N(SiMe3)2}3Me] (M = Zr or Hf ) gave the compounds [M{N(SiMe3)2}3][MeB(C6F5)3]. Crystallographic analyses of these compounds revealed the formation of multicentre bonds between the SiCH3 units of the amide ligands and the otherwise electron-deficient metal centre. The new tris(amide) complexes [M{N(Ph)SiMe3}3Cl] and [M{N(Ph)SiMe3}3Me] (M = Zr or Hf ) have also been synthesized.

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Article information

DOI
https://doi.org/10.1039/A706720H
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 387-392

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Synthesis and crystal structure of the tris(amide) cations [M{N(SiMe3)2}3]+ (M = Zr or Hf ): evidence for M–Si–C interactions

J. R. Galsworthy, M. L. H. Green, N. Maxted and M. Müller, J. Chem. Soc., Dalton Trans., 1998, 387 DOI: 10.1039/A706720H

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