Issue 11, 1997
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Structural investigations of C-nitrosobenzenes. Part 1. Solution state 1H NMR studies

Daniel A. Fletcher,   Brian G. Gowenlock  and  Keith G. Orrell  

Abstract

Ambient and low temperature 1H NMR spectra of a wide range of 3- and 4-monosubstituted, and some di- and tri-substituted C-nitrosobenzenes have enabled –N[double bond, length half m-dash]O substituent constants for the static and rotating ring molecules to be calculated. This has provided information on the shielding anisotropy of the N[double bond, length half m-dash]O group which in turn leads to the firm identification of the monomeric and dimeric solution species. In all cases lowering the solution temperature enhances the relative populations of dimers to monomers, with the (Z)-azodioxy dimer being preferred over the (E)-form, irrespective of the nature of the solid state dimeric structure.

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Article information

DOI
https://doi.org/10.1039/A703760K
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1997, 2201-2206

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Structural investigations of C-nitrosobenzenes. Part 1. Solution state 1H NMR studies

D. A. Fletcher, B. G. Gowenlock and K. G. Orrell, J. Chem. Soc., Perkin Trans. 2, 1997, 2201 DOI: 10.1039/A703760K

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