SCHEDULED MAINTENANCE
One- and two-dimensional organic–inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}2+ fragments (M = Co, Ni, Cu)
Abstract
Hydrothermal reactions of
Na
2
MoO
4
·2H
2
O and MoO
3
with MCl
2
·xH
2
O (M = Co, Ni, Cu) and
2,2′-bipyridine yield one- and two-dimensional solids, characterized
by molybdenum oxide monomers, clusters and chains linked by
{M(2,2′-bpy)}
2+
groups and represented by the
formulae [M(bpy)
x
-
(H
2
O)
y
Mo
n
O
3n
+1
] (n = 2, M = Cu, x= 1, y = 0;
n = 3, M = Co, x = 1, y = 0; n = 4, M
= Ni, x = 2, y = 0).
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