Issue 15, 1997

Hydrothermal synthesis and structural characterization of [Cu(en)2]2Cu7Cl11: a three-dimensional open-framework copper halide with occluded [Cu(en)2]2+ cations

Abstract

A new type of three-dimensional open-framework copper chloride, prepared simply by the hydrothermal treatment of CuCl 2 ·H 2 O and en, is built up from unusual chloride bridged Cu 4 tetramers connected by CuCl 3/3 units and has voids in the framework that are filled with charge-compensating [Cu(en) 2 ] 2+ cations.

Article information

Article type
Paper

Chem. Commun., 1997, 1365-1366

Hydrothermal synthesis and structural characterization of [Cu(en)2]2Cu7Cl11: a three-dimensional open-framework copper halide with occluded [Cu(en)2]2+ cations

J. R. D. DeBord, Y. Lu, C. J. Warren, R. C. Haushalter and J. Zubieta, Chem. Commun., 1997, 1365 DOI: 10.1039/A702053H

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