Haem d1: stereoselective synthesis of the reduced form of its parent macrocycle using the original coupling strategy
Abstract
A substituted isobacteriochlorin, which corresponds structurally
to the reduced metal-free macrocycle of haem d1, has
been synthesised by a stereoselective route in which the final step is a
photochemical 18π-electron antarafacial cyclisation of an
open-chain precursor.
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