Issue 3, 1997

Synthesis of a Sulfur-bridged Calixarene

Abstract

A thiacalix[4]arene was obtained by the reaction of the 2,5-thiophene dianion with SCl 2 ; the analogous reactions of dianions of diaryl thioethers did not yield macrocyclic structures and under the applied conditions diaryl sulfones were further deprotonated and the structure of the fourfold Me 3 Si adduct 11 determined by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Res. (S), 1997, 69-69

Synthesis of a Sulfur-bridged Calixarene

B. König, M. Rödel, I. Dix and P. G. Jones, J. Chem. Res. (S), 1997, 69 DOI: 10.1039/A607416B

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