Issue 11, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

The crystal and molecular structures of 1-naphthylphenyliodonium tetrafluoroborate and 1-naphthylphenyliodonium tetrakis(pentafluorophenyl)gallate†

Bilal R. Kaafarani,a   Haiyan Gu,a   A. Alan Pinkertonb  and  Douglas C. Neckers*a  

* Corresponding authors

a Center for Photochemical Sciences, Bowling Green State University, Bowling Green, Ohio 43403, USA
E-mail: neckers@photo.bgsu.edu

b Department of Chemistry, University of Toledo, Toledo, Ohio, 43606, USA

Abstract

The X-ray structures of 1-naphthylphenyliodonium tetrafluoroborate 1 and 1-naphthylphenyliodonium tetrakis(pentafluorophenyl)gallate 2 are reported. Crystals of 1 are monoclinic, space group P2(1)/c, with unit cell dimensions a = 11.8914(11), b = 8.8699(9), c = 14.4445 (13) Å, β = 90.944(4)°, Z = 4, and R = 0.0596 for 8286 unique observed reflections. Crystals of 2 are monoclinic, space group P2(1)/c, with unit cell dimensions a = 15.003(5), b = 18.287(6), c = 14.738(6) Å, β = 115.436(13)°, Z = 4, and R = 0.0222 for 8063 unique observed reflections. The iodonium cations of 1 exist as π-stacked dimers; however, those of 2 are monomeric.

Graphical abstract: The crystal and molecular structures of 1-naphthylphenyliodonium tetrafluoroborate and 1-naphthylphenyliodonium tetrakis(pentafluorophenyl)gallate

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Article information

DOI
https://doi.org/10.1039/B202805K
Article type
Paper
Submitted
12 Dec 2001
Accepted
26 Mar 2002
First published
25 Apr 2002

J. Chem. Soc., Dalton Trans., 2002, 2318-2321

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The crystal and molecular structures of 1-naphthylphenyliodonium tetrafluoroborate and 1-naphthylphenyliodonium tetrakis(pentafluorophenyl)gallate

B. R. Kaafarani, H. Gu, A. Alan Pinkerton and D. C. Neckers, J. Chem. Soc., Dalton Trans., 2002, 2318 DOI: 10.1039/B202805K

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