Abstract
SYNTHESIS of diamond from graphite in the size range <0.1 to 1 mm requires an ultra-autoclave capable of operating at about 100,000 atm and 2000° K (ref. 1). A molten metal solvent-catalyst is also needed so that the conversion may be achieved in a relatively short time (minutes). Catalysts used include chromium, manganese and tantalum plus all elements of Group VIII of the periodic table, but nickel is used most frequently. The cross hatched region of Fig. 1 shows the combinations of pressure and temperature used for diamond synthesis when nickel is the catalyst.
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KOMANDURI, R., SHAW, M. New method of nucleating diamonds. Nature 248, 582–584 (1974). https://doi.org/10.1038/248582a0
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DOI: https://doi.org/10.1038/248582a0
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