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New Poly(Methacrylate)s Containing Benzylpiperazine and Methylpiperidine Moieties

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Abstract

The synthesıs of two new methacrylate esters containing 2-(4-benzyl piperazin-1-yl)-2-oksoethyl and 2-(4-methylpiperidin-1-yl)-2-oksoethyl group are described. The monomers produced from the reaction of corresponding 4-methylpiperidinechloroacetamide and 1-benzylpiperazinechloroacetamide with sodium methacrylate were polymerized in DMSO solution at 65 °C using AIBN as an initiator. The monomers and their polymers were characterized by IR, 1H- and 13C-NMR spectroscopy. The glass transition temperature of the polymers were investigated by DSC and the apparent thermal decomposition activation energies (E d ) were calculated by Ozawa method using the SETARAM Labsys TGA thermobalance. By using gel permeation chromatography, weight average (\(\overline M _{\rm{w}} \)) and number average (\(\overline M _{\rm{n}} \)) molecular weights and polidispersity, indices of the polymers were determined.

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Authors and Affiliations

  1. Department of Chemistry, Yozgat Faculty of Science and Arts, University of Erciyes, Yozgat, Turkey

    Cengiz Soykan & Yunus Akçamur

  2. Department of Chemistry, Faculty of Science and Arts, University of Afyon Kocatepe, Afyon, Turkey

    İbrahim Erol

  3. Department of Chemistry, Faculty of Science and Arts, University of Harran, Şanlıurfa, Turkey

    Hasan Türkmen

Authors
  1. Cengiz Soykan
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  2. İbrahim Erol
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  3. Hasan Türkmen
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  4. Yunus Akçamur
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Soykan, C., Erol, İ., Türkmen, H. et al. New Poly(Methacrylate)s Containing Benzylpiperazine and Methylpiperidine Moieties. Journal of Polymer Research 11, 181–187 (2004). https://doi.org/10.1023/B:JPOL.0000043400.92054.92

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