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A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

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Abstract

A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of NiII, CuII, CoII and FeII have been prepared and were found to have a metal–ligand ratio of 1:2. The synthesis of di- and trinuclear complexes was achieved with UIVO2 and CuII depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, 1H-n.m.r., u.v.–vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.

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Authors and Affiliations

  1. Department of Chemistry, Sakarya University, Adapazarı, 54100, Sakarya, Turkey

    Mehmet Kandaz & Seher Zerrin Çoruhlu

  2. Department of Chemistry, Istanbul Technical University, Maslak, 80626, Istanbul, Turkey

    İsmail Yilmaz

  3. Department of Chemistry, Marmara University, Kadıköy, 81040, Istanbul, Turkey

    Ali Rıza Özkaya

Authors
  1. Mehmet Kandaz
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  2. Seher Zerrin Çoruhlu
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  3. İsmail Yilmaz
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  4. Ali Rıza Özkaya
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Kandaz, M., Çoruhlu, S.Z., Yilmaz, İ. et al. A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes. Transition Metal Chemistry 27, 877–883 (2002). https://doi.org/10.1023/A:1021359012365

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