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X-ray crystal structure of trans-bis(monoethanolamine) bis(saccharinato)nickel(II)

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Abstract

The crystal structure of trans-bis(monoethanolamine)bis(saccharinato)nickel(II), [Ni(C7H4NO3S)2(C2H7NO)2], has been determined from X-ray diffraction data. The metal complex is monoclinic, with a = 11.0555(5), b = 8.9103(4), c = 11.3890(5) Å, β = 105.0230(10)°, Z = 2, and space group P21/c . The structure consists of individual molecules. Two monoethanolamine molecules and two saccharinate anions coordinate the nickel atom forming a distorted octahedron. The monoethanolamine molecules act as a bidentate ligand and form five-membered trans chelate rings, which constitute the plane of the coordination octahedron, while two saccharinate ions behave as a monodentate ligand occupying the axial positions. Intermolecular hydrogen bonds link the molecules to form a three-dimensional infinite structure.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Kurupelit, Samsun, Turkey

    Omer Andac & Yildiray Topcu

  2. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Kurupelit, Samsun, Turkey

    Veysel T. Yilmaz

  3. Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen, AB24 3UE, Scotland, UK

    William T.A. Harrison

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  1. Omer Andac
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  2. Yildiray Topcu
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  3. Veysel T. Yilmaz
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  4. William T.A. Harrison
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Andac, O., Topcu, Y., Yilmaz, V.T. et al. X-ray crystal structure of trans-bis(monoethanolamine) bis(saccharinato)nickel(II). Journal of Chemical Crystallography 30, 767–771 (2000). https://doi.org/10.1023/A:1013292406687

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