Abstract
The solubility of the gypsum is generally very high in comparison to many other minerals. The surface and groundwater contacting gypsum formations can easily attain high amounts oftotal dissolved solids (TDS), calcium, and sulphate. This composition of the waters prevent their usage for drinking,domestic, industrial and irrigation purposes.Gypsum formations, containing halite (rock salt) interlayers, crop out in a large area in Upper Kızılırmak basin, Sivas, Turkey. In this study, the effects of the lithological composition of the catchment area on the water chemistry and quality were studied on the Upper Kızılırmak basin.Surface waters draining gypsiferous area, and Göydün and Seyfe springs create high TDS concentration in Kızılırmak river (EC = 1100–5200 μS cm-1). Göydün and Seyfe springs which issue from gypsum are very rich in TDS (EC = 12 825–13 900 μS cm-1) and are of poor quality. Surface and groundwater resources in non-gypsiferous part of the basin (Yıldız river, Kaynarca and Gaziköy springs, Tavra valley) have lower TDS and higherquality. EC of these waters range between 495–630, 795–995, and 530–575 μS cm-1, respectively.The Kızılırmak river (with the exception of the upstream part which drains non-gypsiferous area), Göydünand Seyfe springs, and the well in Kızılırmak river alluvium (SK-1) are not suitable for drinking, irrigation and industry. TDS, hardness, sulphate and chloride concentrations of these waters exceed maximum permissible limits for these parameters in Turkish Drinking Water Standards (TDWS). The abovementioned water resources have high to very high salinity and sodium (alkali) hazard from the point of irrigation water quality, and are not also suitable for allmost all industrial usage.
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References
Aktimur, T.: 1988, ‘1/100.000 Ölçekli Aççnsama Nitelikli Türkiye Jeoloji Haritaları Serisi Sivas-F24 Paftası (1/100.000 Scaled Geological Map Series of Turkey-Sivas F-24 Sheet)’, MTA Genel Müdürlüğü (General Directorate of Mineral Research and Exploration, Turkey), 11 p.
Appelo, C. A. J. and Postma, D.: 1996, Geochemistry, Groundwater and Pollution, Balkema, Rotterdam, 536 p.
APHA-AWWA-WPCF: 1981, Standard Methods for the Examination of Water and Wastewater, 15th ed., American Public Health Association, Washington, U.S.A., 1134 p.
Back, W.: 1996, ‘Hydrochemical Facies and Groundwater Flow Patterns in Northern Part of Atlantic Coastal Plain’, U.S. Geological Survey Professional Paper 498-A.
Back, W. and Hanshaw, B. B.: 1970, Journal of Hydrology 10, 330.
Baykal, F. and Erentöz, C.: 1966, ‘1/500 000 Ölçekli Türkiye Jeoloji Haritası-Sivas Paftası’ (1/500 000 Scaled Geological Map of Turkey-Sivas Sheet), MTA Genel Müdürlüğü (General Directorate of Mineral Research and Exploration, Turkey), 116 p.
Bögli, A.: 1980, Karst Hydrology and Physical Speleology, (translated by June C. Schmidt), Springer Verlag, Berlin, 284 p.
Ceyhan, F.: 1987), ‘Sivas Güneydoğusundaki Tuz ve Jips Yataklarının Jeolojisi, Olu¸sumu, Kökeni ve Ekonomik Özellikleri’ (Geology, Formation, Origin and Economic Properties of the Salt and Gypsum Beds to the SE of Sivas), M. Sc. Thesis, Cumhuriyet University, Sivas, 117 p.
Drever, J. I.: 1996, The Geochemistry of Natural Waters, 3rd ed., Prentice Hall, New Jersey, 436 p.
Ford, D. C. and Williams, P. W.: 1989, Karst Geomorphology and Hydrology, Unwin Hyman, London, 601 p.
Freeze, R. A. and Cherry, J. A.: 1979, Groundwater, Prentice-Hall, Englewood Cliffs, NJ, 604 p.
Gökçe, A. and Ceyhan, F.: 1988, Bull. of the Faculty of Eng. Cumhuriyet University, Series A-Earth Sciences 5, 91.
Hem, J. D.: 1985, ‘Study and Interpretation of the Chemical Characteristics of Natural Water’, U.S. Geological Survey, Water Supply Paper 2254, 263 p.
Kaçaroğlu, F. and Şahin, M.: 1994, Yerbilimleri (Geosound) 24, 117.
Kaçaroğlu, F., Değirmenci, M. and Cerit, O.: 1996, Yerbilimleri, Bull. of Earth Sciences Application and Research Centre of Hacettepe University 18, 109.
Kaçaroğlu, F., Değirmenci, M. and Cerit, O.: 1997, Environmental Geology 30, 88.
Kurtman, F.: 1973, MTA Dergisi 80, 1.
Langmuir, D.: 1997, Aqueous Environmental Geochemistry, Prentice Hall, NJ, 600 p.
Mather, J.: 1997, ‘Collection and Analysis of Groundwater Samples’, in Ola M. Saether and Patricia De Caritat (eds.), Geochemical Processes, Weathering and Groundwater Recharge in Catchments, Balkema, Rotterdam, pp. 167–184.
Piper, A. M.: 1944, American Geophysical Union Transactions 25, 914.
Plummer, L. N., Jones, B. F. and Truesdell, A. H.: 1976, ‘WATEQF-AFortran IV Version of WATEQ, A Computer Program for Calculating Chemical Equilibria of Natural Water’, U.S. Geological Survey, Water Resources Investigation Report, 76–13, 61 p.
Richards, L. A. (ed.): 1954, ‘Diagnosis and Improvement of Saline and Alkali Soils’, in Agriculture Handbook 60, U.S. Department of Agriculture, Washington, D.C., 160 p.
Sawyer, C. N. and McCarty, P. L.: 1967, Chemistry for Sanitary Engineers, McGraw-Hill, New York, 518 p.
Todd, D. K.: 1980, Groundwater Hydrology, 2nd ed., John Wiley & Sons, New York, 535 p.
Tucker, M. E.: 1991, Sedimentary Petrology, An Introduction to the Origin of Sedimentary Rocks, 2nd ed., Blackwell Scientific Publ., London, 260 p.
TSE: 1986, Türk İçmesuyu Standartları (Turkish Drinking Water Standards) Türk Standartları Enstitüsü (Turkish Standards Institution), Ankara, 97 p.
White, W. B.: 1988, Geomorphology and Hydrology of Karst Terrains, Oxford Univ. Press, Oxford, 464 p.
White, W. B.: 1997, Environmental Geology 30, 46.
Yılmaz, A.: 1980, Tokat ile Sivas Arasındaki Bölgede Ofiyolitlerin Kökeni, İç Yapısı ve Diğer Birimlerle İlişkisi (The Origin, Internal Structure and Relations to the Other Lithologies of the Ophiolites in the Region Between Tokat and Sivas), Ph. D. Thesis, Ankara University, Ankara, 110 p.
Yılmaz, A.: 1982, ‘Dumanlı Dağı (Tokat) ile Çeltek Dağı (Sivas) Arasının Temel Jeolojik Özellikleri ve Ofiyolitli Karışığın Konumu’ (Main Geological Characteristics of the Region Between Dumanlı Mountain (Tokat) and Çeltek Mountain (Sivas) and the Settling of the Ophiolitic Melange), MTA Genel Müdürlüğü (General Directorate of Mineral Research and Exploration, Turkey), 164 p.
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Kaçaroğlu, F., Değirmenci, M. & Cerit, O. Water Quality Problems of a Gypsiferous Watershed: Upper Kizilirmak Basin, Sivas, Turkey. Water, Air, & Soil Pollution 128, 161–180 (2001). https://doi.org/10.1023/A:1010333522184
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DOI: https://doi.org/10.1023/A:1010333522184