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An Infrared Spectroscopic Study on the Hofmann-diam-type 1,12-Diaminododecanemetal(II) Tetracyanonickelate(II)-aromatic Guest Clathrates: M(H2N(CH2)12NH2)Ni(CN)4ċG(M=Co, Ni or Cd; G = Benzene, Naphthalene, Anthracene, Phenanthrene or Biphenyl)

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Abstract

Three Hofmann-diaminododecane-type clathrates of the form M(1,12-diaminododecane) Ni(CN)4ċG (M = Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl) have been prepared in powder form. The 1,12-diaminododecane molecules in the host lattice permit the inclusion of bulky guest molecules. The spectral features suggest that these compounds are similar in structure to the other Hofmann-diam-type clathrates.

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Authors and Affiliations

  1. Fen Fakültesi, Yunusemre Kampüsü, Anadolu Üniversitesi, TR, 26470, Eskişehir, Turkey

    Mustafa Şenyel & Güneş Kürkçüoğ

  2. Fen Edebiyat Fakültesi, Fizik Bölümü, Gazi Üniversitesi, 06500, Ankara, Turkey

    T. Raci Sertbakan, Ergün Kasap & Ziya Kantarci

Authors
  1. Mustafa Şenyel
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  2. T. Raci Sertbakan
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  3. Güneş Kürkçüoğ
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  4. Ergün Kasap
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  5. Ziya Kantarci
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Correspondence to Ziya Kantarci.

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Şenyel, M., Raci Sertbakan, T., Kürkçüoğ, G. et al. An Infrared Spectroscopic Study on the Hofmann-diam-type 1,12-Diaminododecanemetal(II) Tetracyanonickelate(II)-aromatic Guest Clathrates: M(H2N(CH2)12NH2)Ni(CN)4ċG(M=Co, Ni or Cd; G = Benzene, Naphthalene, Anthracene, Phenanthrene or Biphenyl). Journal of Inclusion Phenomena 39, 175–180 (2001). https://doi.org/10.1023/A:1008141726024

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