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An Infrared Spectroscopic Study of Pyrazine- and 4,4′-bipyridyl-Td-type Clathrates: Mn (pyrazine) M(CN)4 benzene (M = Cd or Hg) and Mn (4,4′-bipyridyl) M(CN)4. benzene (M = Zn, Cd or Hg)

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Abstract

The infrared spectra of the title compounds have been reported. The spectral data suggest that the host framework of these compounds are similar to those of the en-Td-type clathrate compounds. There is good evidence for hydrogen bonding from ligand molecules to benzene molecules as a π to σ hydrogen bond.

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Authors and Affiliations

  1. Fen Edebiyat Fakültesi, Fizik Bölümü, Gazi Üniversitesi, 06500, Ankara, Turkey.

    Ziya Kantarci, Celal Batyak & Burhan Davarcioĝlu

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  1. Ziya Kantarci
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  2. Celal Batyak
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  3. Burhan Davarcioĝlu
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Correspondence to Ziya Kantarci.

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Kantarci, Z., Batyak, C. & Davarcioĝlu, B. An Infrared Spectroscopic Study of Pyrazine- and 4,4′-bipyridyl-Td-type Clathrates: Mn (pyrazine) M(CN)4 benzene (M = Cd or Hg) and Mn (4,4′-bipyridyl) M(CN)4. benzene (M = Zn, Cd or Hg). Journal of Inclusion Phenomena 39, 115–121 (2001). https://doi.org/10.1023/A:1008127407158

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