Abstract
A new series of macrocyclic imine-oxime complexes prepared by template condensation of o-phenylenediamine, phthaldialdehyde, 2,6-diacetylpyridine and dichloroglyoxime in MeOH solution, have been characterized by i.r., electronic spectral data, elemental analyses, conductivity and magnetic susceptibility measurements. In the imine moiety of the complexes, the chloride ions coordinate to the nickel ion. From conductivity measurements, it was shown that the complexes are not all electrolytes. Their thermal behaviour has been studied by the t.g. and d.t.a. analysis. They decompose with loss of the organic ligand and halogen to leave the metal oxide.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
N.F. Curtis, Coord. Chem. Rev., 3, 3 (1968).
L. Casella, M. Gullotti, L.D. Gioia, E. Monzani and F. Chillemi, J. Chem. Soc. Dalton Trans., 2945 (1991).
K.R. Adam, M. Antolovich, D.S. Baldwin, L.G. Brgden, P.A. Duckworth, L.F. Lindoy, A. Bashall, M. McPartlin and P.A. Tasker, J. Chem. Soc. Dalton Trans., 1869 (1992).
B.J. Hathaway and D.E. Billing, Coord. Chem. Rev., 5, 143 (1970).
M. de S. Healen and A.J. Rest, Adv. Inorg. Chem. Radiochem., 21, 1 (1978).
L.F. Lindoy, The Chemistry of Macrocyclic Ligand Complexes, Cambridge University Press, Cambridge, 1989.
K.R. Adam, M. Antolovich, D.S. Baldwin, L.G. Brgden, P.A. Duckworth, L.F. Lindoy, A. Bashall, M. Mcpartlin and P.A. Tasker, J. Chem. Soc., Dalton Trans., 1869 (1992).
M. Manjushere and C.D. Kailash, Indian J. Chem., 29, 482 (1990).
W.J. Geary, Coord. Chem. Rev., 7, 81 (1971).
M. Tümer, C. Çelik, H. Köksal and S. Serin, Transition Met. Chem., 24, 525 (1999).
M. Tümer, M.K. üener, H. Köksal and S. Serin, Transition Met. Chem., 24, 414 (1999).
M. Tümer, H. Köksal, S. Serin and M. Diğrak, Transition Met. Chem., 24, 13 (1999).
M. Tümer, H. Köksal and S. Serin, Synth. React. Inorg. Met.-Org. Chem., 27, 775 (1997).
M. Tümer, B. Erdoğan, H. Köksal, S. Serin and M.Y. Nutku, Synth. React. Inorg. Met.-Org. Chem., 28, 529 (1998).
M. Tümer, H. Köksal and S. Serin, Synth. React. Inorg. Met.-Org. Chem., 28, 1393 (1998).
V. Alexandar, Inorg. Chim. Acta, 204, 109 (1993).
H. Köksal, M. Tümer and S. Serin, Synth. React. Inorg. Met.-Org. Chem., 26, 1977 (1996).
J.R. Allan, N.D. Baird and A.L. Kassyk, J. Therm. Anal., 16, 79 (1979).
M. Tümer, H. Köksal and S. Serin, Synth. React. Inorg. Met.-Org. Chem., 26, 1989 (1996).
M. Tümer, H. Köksal, S. Serin and Ş. Patat, Synth. React. Inorg. Met.-Org. Chem., 27, 59 (1997).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Çolak, A.T., Tümer, M. & Serin, S. Nickel ion as a template in the synthesis of macrocyclic imine-oxime complexes from carbonyl compounds and o-phenylenediamine. Transition Metal Chemistry 25, 200–204 (2000). https://doi.org/10.1023/A:1007030418949
Issue Date:
DOI: https://doi.org/10.1023/A:1007030418949