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Electronic Absorption Spectra and Tautomerism of Quinizarin and Its Substituted Derivatives

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Abstract

According to the data of quantum-chemical calculations and correlation analysis, the experimental electronic absorption spectra of quinizarin and its substituted derivatives contain bands corresponding to 9,10-, 1,10-, and 1,4-anthraquinoid tautomers. Analysis of the absorption spectra revealed specific features of the tautomeric structure of substituted quinizarins.

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  1. Russian University of Peoples Friendship, Moscow, Russia

    V. Ya. Fain, B. E. Zaitsev & M. A. Ryabov

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  1. V. Ya. Fain
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  2. B. E. Zaitsev
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  3. M. A. Ryabov
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Fain, V.Y., Zaitsev, B.E. & Ryabov, M.A. Electronic Absorption Spectra and Tautomerism of Quinizarin and Its Substituted Derivatives. Russian Journal of General Chemistry 73, 1595–1602 (2003). https://doi.org/10.1023/B:RUGC.0000016029.81183.33

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  • DOI: https://doi.org/10.1023/B:RUGC.0000016029.81183.33

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