Abstract
Soluble cationic organoiron polynorbornenes with pendent hetarylazo side chains have been synthesized via ring opening metathesis polymerization (ROMP) using bis(tricyclohexylphosphine)benzylideneruthenium(IV) dichloride (Grubbs' catalyst). The vibrantly colored organoiron polymers displayed weight average molecular weights between 24500 and 40900 and exhibited glass transition temperatures at 146 °C and 161 °C.
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Abd-El-Aziz, A.S., Okasha, R.M. & Afifi, T.H. First Example of Benzothiazole Azo Dyes Containing Cyclopentadienyliron Polynorbornene Macromolecules. Journal of Inorganic and Organometallic Polymers 14, 269–278 (2004). https://doi.org/10.1023/B:JOIP.0000048031.82464.ac
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DOI: https://doi.org/10.1023/B:JOIP.0000048031.82464.ac